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Zipped up: Supramolecular 3D organization on gold with interdigitating intra‐ and interlayer recognition motifs (see picure, black p‐oligophenyl rods; red, blue naphthalenediimide (NDI) stacks) is designed to access supramolecular cascade n/p‐heterojunctions or the adaptable directionality needed to control fill factors in current–voltage curves.

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